What role does dilute nitric acid play when testing for halides?

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Dilute nitric acid plays a crucial role in the testing for halides by ensuring the formation of clear precipitates. When testing for halides such as chloride, bromide, and iodide ions, the addition of dilute nitric acid helps to remove any interfering ions present in the solution, particularly carbonate ions. These carbonate ions can lead to the formation of unwanted precipitates if they are not removed.

By acidifying the solution with dilute nitric acid, it allows the subsequent addition of silver nitrate to form well-defined precipitates of silver halides, such as white for silver chloride or cream for silver bromide. This clear formation of precipitates is essential for visual identification and confirmation of the presence of halide ions.

The other options do not accurately describe the function of dilute nitric acid in this context. It does not act as a reducing agent, nor does it neutralize the solution in a traditional sense, as it is primarily used to acidify the solution rather than to neutralize a base. Additionally, it does not increase the viscosity of the sample; its primary function relates to the removal of ions that could interfere with the clarity and accuracy of the halide test results.

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